Size effect in the titanium/diamond-like carbon bilayer films: effect of relative thickness on their structure and mechanical properties

作者：Zhou, B.^*; Liu, Z.; Rogachev, A. V.; Piliptsou, D. G.; Tang, B.

来源：Surface and Interface Analysis, 2017, 49(1): 47-54.

DOI：10.1002/sia.6056

• diamond-like carbon
• size effect
• bilayer
• microstructure
• mechanical property

Titanium/diamond-like carbon (Ti/DLC) bilayer films with different relative thickness were fabricated by direct-current and pulsed cathode arc plasma method. Microstructure, morphological characteristics, and mechanical properties of the films were investigated in dependence of the thickness of Ti and DLC layers by Raman spectroscopy, atomic force microscopy, Knoop sclerometer, and surface profilometer. Raman spectra of Ti/DLC bilayers show the microstructure evolution (the size and ordering degree of sp(2)-hybridized carbon clusters) with varying the thicknesses of Ti interlayer and DLC layer. Nano-scaled Ti interlayer of 12-20 nm thickness presents the largest size effect. The catalytic effect of the sublayer is most pronounced in the carbon layer of less than 106 nm. In these thickness ranges, the bilayer films possessed the highest micro-hardness and reactivity between atoms at interface. Internal stress in the bilayer monotonically decreases, with the thickness of Ti interlayer increasing to 30 nm and then becomes stable with the thickness. These results are associated with the occurrence of atomic diffusion process at Ti/C interface, and they are of cardinal significance to optimize the structure and mechanical properties of carbon-based multilayer films.

• 出版日期2017-1
• 单位太原理工大学