科研之友
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摘要
A new complex [UO2(2,6 DNP)(2)phen] (1) (2,6 DNP = 2,6 dinitrophenol, phen = 1,10 phenanthroline) was synthesized, and identified by elemental analysis, IR, Powder XRD and single crystal X-ray crystallography. Crystal structure provides the abundant information's about the bonding and geometry around the U(VI) metal center. The thermal decomposition was studied by TG DSC, and the kinetics of thermolysis was investigated by applying model fitting as well as isoconversional methods. Explosion delay measurement (D-e) was also evaluated to determine the response of this complex under the condition of rapid heating.
