摘要

The solvothermal reaction of elemental zinc with sulfur in ethylenediamine ( en) as solvent yields [ZnS.0.5(NH2CH2CH2NH2)], 1, an unprecedented ethylenediamine pillared ZnS layered compound, containing two dimensional (2-D) boat-type 6-membered rings, which was characterized by ab initio structure solution from powder diffraction data (SDPD).

  • 出版日期2003