A structural study of late transition metal diethylenetriamine complexes

作者：Junk Peter C^*; Steed Jonathan W

来源：Inorganica Chimica Acta, 2007, 360(5): 1661-1668.

DOI：10.1016/j.ica.2006.09.001

• diethylenetriamine
• nickel
• copper
• zinc
• coordination complexes
• X-ray crystal structures

The synthesis and X-ray crystal structures of u-fac-[Ni(dien)(2)](NO3)(2), s-fac-[Ni(dien)(2)](tos)(2), fac-fac-[(H2O)(dien)Ni(mu-Cl)(2)(dien)-(H2O)]Cl-2, s-fac-[Ni(dien)(2)][ZnCl4], mer-[Ni(dien)(2)][CdCl4] . H2O, fac-[Ni(dien)(H2O)(3)](tos)(2) . (H2O), mer-[Cu(dien)(H2O)]tos)(2), fac-[Zn(dien)(H2O)(2)](tos)(2) (dien = bis(2-aminoethyl)amine = diethylenetriamine; tos = p-toluenesulfonate) are described. The mode of binding of the tridentate amine is examined in detail.

• 出版日期2007-4-1