摘要

Being poorly known, the ion chemistry of the lower stratosphere is generally ignored, or treated as similar to that of the middle atmosphere, by the current chemistry-climate modes. Some recent achievements in atmospheric chemistry have motivated us to re-asses the ionization efficiency of galactic cosmic rays (OCR) and ion-molecular reaction initiated by them. We reveal that near to the maximum of the GCR absorption, the energetically allowed ion-molecular reactions form an autocatalytic cycle for continuous O-3 production in the lower stratosphere. The amount of the produced ozone is comparable to the values of the standard winter time O-3 profile. This is an indication that GCR are responsible for a greater part of the lower stratospheric ozone variability then is assumed currently.

  • 出版日期2013

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