An organogel system can control the stereochemical course of anthracene photodimerization

作者:Dawn Arnab; Fujita Norifumi*; Haraguchi Shuichi; Sada Kazuki; Shinkai Seiji
来源:Chemical Communications, 2009, (16): 2100-2102.
DOI:10.1039/b820565e

摘要

A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.

  • 出版日期2009