Mechanical behavior, structure, and reinforcement processes of TEMPO-oxidized cellulose reinforced poly(lactic) acid

作者：Bulota Mindaugas^*; Vesterinen Arja Helena; Hughes Mark; Seppala Jukka

来源：Polymer Composites, 2013, 34(2): 173-179.

DOI：10.1002/pc.22390

Poly(lactic) acid (PLA) was reinforced with acetylated TEMPO-oxidized fibrillated cellulose (TOFC) prepared from birch pulp. Composite films were studied using dynamic mechanical thermal analysis, differential scanning calorimetry (DSC), as well as static mechanical testing. The storage modulus as well as tensile strength of PLA was improved on the addition of 30 wt% of TOFC by approximately 50% and 40%, respectively. Thermal stability as well as strength properties in moist environments (up to 90% relative humidity) was significantly improved at 15, 20, 25, and 30 wt% of TOFC. DSC showed that crystallization from solution took place during preparation of the composite films and was much greater than melt crystallization. POLYM. COMPOS., 2012.

• 出版日期2013-2