Dual-membrane reactor for methane oxidative coupling and dry methane reforming: Reactor integration and process intensification

作者：Godini H R^*; Xiao S; Kim M; Goerke O; Song S; Wozny G

来源：Chemical Engineering and Processing, 2013, 74: 153-164.

DOI：10.1016/j.cep.2013.09.007

• Dual-membrane reactor
• Oxidative coupling of methane
• Dry methane reforming
• Reactor integration
• Integrated process structure

A novel dual-membrane reactor concept was introduced for integrating the oxidative coupling of methane (OCM) and CO2 methane reforming (dry reforming) reactors. The OCM reactions occur in a conventional porous packed bed membrane reactor structure and a portion of the undesired produced CO2 and generated heat are transferred through a molten-carbonate perm-selective membrane and consumed in the adjacent dry methane reforming catalytic bed. This integrated reactor provides a very promising thermal performance by controlling the temperature peak to be below 50 C in reference to the average operating temperature in the OCM section. This was achieved even for the low methane-to-oxygen ratio 2 by introducing 10% CO2 as the diluent agent and reactant in this integrated reactor structure. This contributed to the improved selective performance of 32% methane conversion and 25% C-2-yield including 21% C2H4-yield in the OCM section which also enhances the performance of the downstream units consequently. Around half of the unconverted methane leaving the OCM section was converted to syngas in the DRM section.
The dual-membrane reactor alone can utilize a significant amount of the carbon dioxide generated in the OCM catalytic bed. In combination with adsorption unit in the downstream of the integrated process, 90% of the produced CO2 can be recovered and further converted to valuable syngas products. The experimental data, obtained from a mini-plant scale experimental facility, were exploited to verify the performance of the OCM reactor and the CO2 separation section.

• 出版日期2013-12