Alkylation of CH Acids with Haloidalkyl-1,3-dioxolanes

作者:Raskil'dina G Z*; Borisova Yu G; Spirikhin L V; Zlotsky S S
来源:Russian Journal of General Chemistry, 2017, 87(5): 1097-1100.
DOI:10.1134/S1070363217050358

摘要

Alkylation of diethyl malonate and Meldrum acid with haloalkyl-1,3-dioxolanes has afforded the substituted malonates; their decarboxylation has led to the formation of esters containing a cycloacetal fragment. Reactions of the substituted malonates with urea have yielded the corresponding substituted barbiturates. Monodecarboxylation of the obtained malonates has led to the formation of 1,3-dioxolane-carboxylates.

  • 出版日期2017-5

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