科研之友
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摘要
We present a new route for the synthesis of Ag nanopore-inlaynanogap structures using creviced graphene-shell encapsulated Cu nanoparticles (Cu@ G-NPs) as the sacrificial templates. The as-synthesized integrated Ag-core@graphene-shell@Ag-jacket nanoparticles (AgC@G@AgJ-NPs) presents "chrysanthemum'' shapes that contain abundant sub-10 nm size intraparticle nanopores/nanogaps, which can generate huge enhanced electromagnetic fields to support SERS activity, resulting in an average EF 4 107 due to a high-density of intraparticle and interparticle "hot spots''.
