Aldehyde allylation with allylboronates providing alpha-addition products

作者:Kobayashi Shue*; Endo Toshimitsu; Schneider Uwe; Ueno Masaharu
来源:Chemical communications, 2010, 46(8): 1260-1262.
DOI:10.1039/b924527h

摘要

Zn(OH)(2)-catalyzed allylation reactions of allylboronates with aldehydes proceeded smoothly in aqueous media; when alpha-substituted allylboronates were employed, the a-addition products were obtained exclusively, and syn-adducts were formed selectively in most cases; the use of Zn(OH)(2) with dmp (ligand) in aqueous media is the key to these reactions.

  • 出版日期2010