Anthrone complexation with aliphatic amines in an aprotic medium

作者:Serdyuk A A*; Abakumov A A; Kapitanov I V; Kasianczuk M G; Opeida I A
来源:Russian Journal of Physical Chemistry, 2013, 87(9): 1470-1473.
DOI:10.1134/S0036024413090203

摘要

Aromatic ketone (anthrone) complexation with aliphatic amines is studied by UV-Vis, H-1, H-1-H-1 COSY NMR spectroscopy. It is found that the catalytic activity of aliphatic amine is observed in the reaction of anthrone oxidation by molecular oxygen in aprotic media due to the formation of intermolecular complexes consisting of two anthrone molecules and one aliphatic amine molecule.

  • 出版日期2013-9

全文