A Flux-Gradient System for Simultaneous Measurement of the CH4, CO2, and H2O. Fluxes at a Lake-Air Interface

作者：Xiao, Wei; Liu, Shoudong; Li, Hanchao; Xiao, Qitao; Wang, Wei; Hu, Zhenghua; Hu, Cheng; Gao, Yunqiu; Shen, Jing; Zhao, Xiaoyan; Zhang, Mi; Lee, Xuhui^*

来源：Environmental Science & Technology, 2014, 48(24): 14490-14498.

DOI：10.1021/es5033713

• GAS TRANSFER VELOCITY
• TUNABLE DIODE-LASER
• METHANE EMISSIONS
• EDDY COVARIANCE
• CARBON-DIOXIDE
• GREENHOUSE GASES
• LITTORAL-ZONE
• WATER
• EXCHANGE
• ATMOSPHERE

Inland lakes play important roles in water and greenhouse gas cycling in the environment. This study aims to test the performance of a flux-gradient system for simultaneous measurement of the fluxes of water vapor, CO2, and CH4 at a lakeair interface. The concentration gradients over the water surface were measured with an analyzer based on the wavelength-scanned cavity ring-down spectroscopy technology, and the eddy diffusivity was measured with a sonic anemometer. Results of a zero-gradient test indicate a flux measurement precision of 4.8 W m(2) for water vapor, 0.010 mg m(-2) s(-1) for CO2, and 0.029 mu g m(-2) s(-1) for CH4. During the 620 day measurement period, 97%, 69%, and 67% of H2O, CO2, and CH4 hourly fluxes were higher in magnitude than the measurement precision, which confirms that the flux-gradient system had adequate precision for the measurement of the lakeair exchanges. This study illustrates four strengths of the flux-gradient method: (1) the ability to simultaneously measure the flux of H2O, CO2, and CH4; (2) negligibly small density corrections; (3) the ability to resolve small CH4 gradient and flux; and (4) continuous and noninvasive operation. The annual mean CH4 flux (1.8 g CH4 m(-2) year(-1)) at this hypereutrophic lake was close to the median value for inland lakes in the world (1.6 g CH4 m(-2) year(-1)). The system has adequate precision for CH4 flux for broad applications but requires further improvement to resolve small CO2 flux in many lakes.

• 出版日期2014-12-16
• 单位南京信息工程大学