A Bromide-bridged Platinum(II) Complex as Precursor to a Neutral Platinum Compound with a Base-Stabilized Borylene Ligand

作者：Braunschweig Holger^*; Brenner Peter; Radacki Krzysztof

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2009, 635(13-14): 2089-2092.

DOI：10.1002/zaac.200900122

• Boron
• Borylene complexes
• Platinum
• Bromine
• Coordination chemistry

The bromide-bridged dinuclear platinum complex [(Cy(3)P){Br(Fc)B}Pt(mu-Br)](2)(1) (Fc = ferrocenyl) was synthesized by the abstraction of PCy(3) from trans-[(Cy(3)P)(2)Pt{(B(Fc)Br}Br] with concomitant build tip of the phosphine borane adduct. This Compound was shown to be a precursor for the first neutral base-stabilized platinum borylene complex cis-[Br(2)Pt(PCy(3)){B(Fc)NC(5)H(4)-4-Me}](2). All compounds were characterized by multinuclear NMR spectroscopy in solution and single crystal crystallographic analysis.

• 出版日期2009