Alkyl-functionalization of 3,5-bis(2-pyridyl)-1,2,4,6-thiatriazine

作者:Kleisath Elizabeth; Yutronkie Nathan J; Korobkov Ilia; Gabidullin Bulat M; Brusso Jaclyn L
来源:New Journal of Chemistry, 2016, 40(5): 4472-4479.
DOI:10.1039/c5nj02611c

摘要

A versatile synthetic route to prepare alkyl functionalized 3,5-bis-(2-pyridyl)-1,2,4,6-thiatriazines is described that can proceed either via cationic or anionic pathways; confirmed through characterization of the isolable intermediates. Computational studies are presented, which support the regioselectivity of the alkylation reactions and photophysical properties of the S-alkylated derivatives.

  • 出版日期2016