Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

作者：Izquierdo Frederic; Chartoire Anthony; Nolan Steven P^*

来源：ACS Catalysis, 2013, 3(10): 2190-2193.

DOI：10.1021/cs400533e

• palladium
• N-heterocyclic carbenes (NHCs)
• arylation
• sulfoxide
• cross-coupling

The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides in moderate to good yields (17 examples, 34-85%). Scope, limitations, and reaction mechanism are discussed.

• 出版日期2013-10