A new 2D Co-5-cluster based MOF: Crystal structure, magnetic properties and electrocatalytic hydrogen evolution reaction

作者：Tian, Jun-Wu; Fu, Meng-Xi; Huang, Dan-Dan; Wang, Xiao-Kun; Wu, Ya-Pan; Lu, Jack Y.^*; Li, Dong-Sheng^*

来源：Inorganic Chemistry Communications, 2018, 95: 73-77.

DOI：10.1016/j.inoche.2018.07.009

• 3,5-bis(3 '-carboxyphenyl)-1,2,4-triazole
• Co-MOF
• Crystal structure
• Magnetic properties
• Hydrogen evolution reaction

A new 2D MOF with unique [Co-5(mu(3)-OH)(2)](8+) subunit, [Co-5(mu(3)-OH)(2)(bcpt)(4)(bib)(2)] (1) (H(2)bcpt = 3,5-bis(3'-carboxyphenyl)-1,2,4-triazole, bib = 1,4-bis(1-imidazoly)benzene) is prepared, which not only shows weak antiferromagnetic interaction between the adjacent Co(II) ion, but also exhibits efficient electrocatalytic hydrogen evolution reaction by the integration with graphene (Gr).

• 出版日期2018-9
• 单位三峡大学; 西安工业大学