N,N-Dimethylpyridin-4-Amine Mediated Protocol for Cyanoethoxycarbonylation of Aldehydes Under Solvent-Free Conditions

作者：Khan Noor ul H^*; Agrawal Santosh; Kureshy Rukhsana I; Bera Prasanta K; Abdi Sayed H R; Bajaj Hari C

来源：Catalysis Letters, 2010, 137(3-4): 255-260.

DOI：10.1007/s10562-010-0355-7

• N, N-dimethylpyridin-4-amine
• Cyanoethoxycarbonylation
• Aldehydes
• Solvent-free
• Ethylcyanoformate

N, N-Dimethylpyridin-4-amine (DAMP) (10 mol%) was successfully employed as catalyst for cyanoethoxycarbonylation of aromatic and aliphatic aldehydes at room temperature under solvent free condition to give corresponding ethylcyanocarbonates in excellent isolated yield (up to 95%) in 15-90 min. Simple experimental conditions and product isolation procedure has made this protocol quite attractive for the synthesis of ethylcyanocarbonates in an environment-friendly manner.

• 出版日期2010-7
• 单位海洋化工研究院有限公司