An All Solid-State Zinc-Air Battery with a Corrosion-Resistant Air Electrode

作者：Devendrachari Mruthyunjayachari Chattanahalli; Basappa Chidananda; Thimmappa Ravikumar; Bhat Zahid Manzoor; Kotresh Harish Makri Nimbegondi; Kottaichamy Alagar Raja; Varhade Swapnil; Khaire Siddhi; Reddy Kallam Ramareddy Venugopala^*; Thotiyl Musthafa Ottakam^*

来源：ChemElectroChem, 2018, 5(14): 1817-1821.

DOI：10.1002/celc.201800269

• corrosion resistance
• molecular catalysts
• titanium nitride
• zinc-air batteries

We illustrate an all solid-state Zn-air battery by utilizing the ability of a titanium-nitride-functionalized molecular catalyst to mediate the oxygen reduction reaction by avoiding the parasitic corrosion chemistry and the hydroxide-holding capacity of the Zirfon membrane. The efficient ionic communication between the half-cell electrodes provided by the Zirfon membrane in combination with the chemical/electrochemical stability of the TiN-based air electrode ultimately led to an all solid-state and air-breathing battery possessing high durability and stability.

• 出版日期2018-7-11