A new metal-organic framework with ultra-high surface area

作者：Gruenker Ronny; Bon Volodymyr; Mueller Philipp; Stoeck Ulrich; Krause Simon; Mueller Uwe; Senkovska Irena; Kaskel Stefan^*

来源：Chemical communications, 2014, 50(26): 3450-3452.

DOI：10.1039/c4cc00113c

A new mesoporous MOF, Zn4O(bpdc)(btctb)(4/3) (DUT-32), containing linear ditopic (bpdc(2-); 4,4'-biphenylenedicarboxylic acid) and tritopic (btctb(3-); 4,4',4 ''-[benzene-1,3,5-triyltris(carbonylimino)]tris-benzoate) linkers, was synthesised. The highly porous solid has a total pore volume of 3.16 cm(3) g(-1) and a specific BET surface area of 6411 m(2) g(-1), adding this compound to the top ten porous materials with the highest BET surface area.

• 出版日期2014