A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

作者:Lin Zhuojia; Wragg David S; Lightfoot Philip; Morris Russell E*
来源:Dalton Transactions, 2009, (27): 5287-5289.
DOI:10.1039/b904450g

摘要

Ionothermal synthesis using a deep eutectic solvent has been used for the first time to prepare a borate-containing material. The metallophosphate-borate compound crystallises in chiral space group I222. Two different alkyl ammonium cations derived from the ionic liquid have distinct template effects on the formation of cobalt phosphate layers and hydrophobic borate channels.

  • 出版日期2009