A new 2D → 2D interpenetrating polymer containing polyrotaxane- and polycatenane-like motifs: The tilt of local distortion axes for the magnetic behavior

作者：Wu, Jian; Liu, Jian-Qiang^*; Wang, Yao-Yu; Gou, Zhan-Ping; Xu, Dao-Hua; Sakiyama, Hiroshi

来源：Inorganic Chemistry Communications, 2012, 25: 10-13.

DOI：10.1016/j.inoche.2012.07.030

• Interpenetration
• Carboxylate
• Topology
• Magnetism

The synthesis, structure and magnetic property of a new coordination network {[Co-2(bcp)(2)(bipy)]}(n) (1) (H(2)bcp=1,3-bis(4-carboxy-phenoxy)propane and bipy=4.4'-pyridine), are reported. Compound 1 shows two identical 2D layers with 2(2).4(8).6(5) topology which are interpenetrated in a parallel fashion, resulting in a twofold interpenetrating motif containing polyrotaxane and polycatenane characters. Magnetic susceptibility indicated the antiferromagnetic exchange interaction. The magnetic behavior of 1 can be explained by the tilts of local distortion axes.

• 出版日期2012-11
• 单位西北大学; 广东医科大学; 广西民族大学