A Mn36Ni4 %26apos;loop-of-loops-and-supertetrahedra%26apos; aggregate possessing a high S-T=26 +/- 1 spin ground state

作者：Charalambous Maria; Moushi Eleni E; Papatriantafyllopoulou Constantina; Wernsdorfer Wolfgang; Nastopoulos Vassilios; Christou George; Tasiopoulos Anastasios J^*

来源：Chemical Communications, 2012, 48(44): 5410-5412.

DOI：10.1039/c2cc30654a

The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a (Mn28Mn8Ni4II)-Mn-III-Ni-II molecular aggregate which consists of two (Mn8Ni2)-Ni-III loops and two (Mn6Mn4II)-Mn-III supertetrahedral units and displays a high ground spin state value S-T = 26 +/- 1.

• 出版日期2012