Analysis of Sulfidic Linkages in Solvent-Extracted Sulfur Cross-Linked Isoprene Rubber

作者：Yasuda Yoritaka^*; Tohsan Atitaya; Limphirat Wanwisa; Ikeda Yuko

来源：Kobunshi Ronbunshu, 2015, 72(1): 16-21.

DOI：10.1295/koron.2014-0065

• Sulfidic Linkage
• Sulfur K-edge XANES
• Isoprene Rubber
• Solvent Extraction

For the first time, sulfur K-edge X-ray absorption near-edge structure (S K-edge XANES) measurement was conducted at room temperature to evaluate a kind of the sulfidic linkage in solvent-extracted sulfur cross-linked isoprene rubbers. The vulcanizates were prepared by heat-pressing of the rubber compounds containing zinc oxide, stearic acid, N-cyclohexyl-2-benzothiazole sulfonamide and sulfur. The sulfidic linkage varied from a polysulfide type to a disulfide type with increasing of the torque during curing. A monosulfide type was also suggested to be generated from the disulfidic linkage. The S K-edge XANES measurement will be of use for evaluating a characteristic of the sulfidic linkages in the sulfur cross-linked rubber by combining the solvent extraction technique.

• 出版日期2015