A 3-D net based on weak metallophilic (Cu center dot center dot center dot Cu) interactions

作者：Zhou, Jian^*; Tan, Xiaofeng; Hu, Feilong; Zou, Hua-Hong; Almeida Paz, Filipe A.; Fu, Lianshe^*; Zhao, Rongqing

来源：Dalton Transactions, 2016, 45(28): 11292-11296.

DOI：10.1039/c6dt00883f

• THERMOCHROMIC-LUMINESCENCE
• SOLVOTHERMAL SYNTHESIS
• COORDINATION POLYMERS
• ELECTRONIC-STRUCTURE
• CRYSTAL-STRUCTURES
• COPPER(I)
• COMPLEXES
• CLUSTER
• PHOTOLUMINESCENCE
• SANDWICH

A novel 3-D binary copper(I) polymer [Cu(IN)](n) (1, IN = isonicotinate) has been solvothermally synthesized. 1-D [Cu(IN)] chains of 1 are interconnected by weak metallophilic (Cu center dot center dot center dot Cu) interactions to form a 3-D net. The theoretical band structure and photocatalytic and fluorescence properties have also been studied.

• 出版日期2016
• 单位重庆师范大学; 广西民族大学; 广西师范大学