Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

作者：Yoo Houng Silk; Kim Jae Il; Yang Namgeun; Koh Eui Kwan; Park Je Geun; Hong Chang Seop^*

来源：Inorganic Chemistry, 2007, 46(22): 9054-9056.

DOI：10.1021/ic7014995

A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N-3)(2)]-MeCN (1 center dot MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

• 出版日期2007-10-29