Achiral Cyclopentadienone Iron Tricarbonyl Complexes Embedded in Streptavidin: An Access to Artificial Iron Hydrogenases and Application in Asymmetric Hydrogenation

作者：Merel Delphine S; Gaillard Sylvain; Ward Thomas R; Renaud Jean Luc

来源：Catalysis Letters, 2016, 146(3): 564-569.

DOI：10.1007/s10562-015-1681-6

• Homogeneous catalysis
• Hydrogenation
• Bio-inspired
• Asymmetric catalysis

We report on the synthesis of biotinylated (cyclopentadienone) iron tricarbonyl complexes, the in situ generation of the corresponding streptavidin conjugates and their application in asymmetric hydrogenation of imines and ketones.

• 出版日期2016-3