A novel interpenetrating 2-D brush-like structure: hydrothermal synthesis and crystal,structure of [Cu(phen)V4O10](infinity) (phen=1,10-phenanthroline)

作者：Cui, XB; Lin, ZE; Yang, GY^*

来源：Solid State Sciences, 2003, 5(2): 311-315.

DOI：10.1016/S1293-2558(03)00006-2

• vanadium oxide
• inorganic-organic hybrid material
• hydrothermal synthesis
• crystal structure

A novel vanadium oxides [Cu(phen)V4O10](infinity) (1), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, EPR spectroscopy and thermal analysis. The compound crystallizes in monoclinic structure of P2(1)/m with a = 7.4169(10) Angstrom, b = 10.0460(13) Angstrom, c = 11.0845(15) Angstrom, beta = 102.520(2)degrees, V = 806.27(19) Angstrom(3) and Z = 2.

• 出版日期2003-2
• 单位中国科学院福建物质结构研究所; 结构化学国家重点实验室; 南京大学; 现代配位化学国家重点实验室