科研之友
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摘要
In this study a click chemistry approach was used to synthesize polyoxometalate-polymer hybrids with well-defined structures. The starting materials were a two-azido-containing organosilyl derivative of a Wells-Dawson-type polyoxometalate and a propargylterminated poly(3-caprolactone). The clicking reaction between the azido groups and alkynyl groups was found to be very efficient and the structures of the hybrids were well-defined. This breakthrough will promote a great development in the synthesis of various polyoxometalate-polymer hybrids and broaden their potential application.
- 出版日期2012
- 单位南开大学
