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摘要
We report the first example of difluoroalkylation/C-H annulation cascade reactions of cyclopropyl olefins induced by visible-light photoredox catalysis regioselectively affording partially hydrogenated naphthalenes and quinolines with a variety of difluorinated side chains. The alkylation reagent could be extended to monofluoro and trifluoro reagents, nitrite and malonate. The regioselectivity was investigated by means of density functional theory calculations.
- 出版日期2016-10-21
- 单位南京大学
