Uranium(VI) metal-organic framework with atropisomeric dicarboxylic ligand

作者：Qu Zhi Rong^*

来源：Chinese Journal of Inorganic Chemistry, 2007, 23(12): 2126-2127.

• uraniuin(VI) complex
• hydrothermal treatment
• crystal structure

Uranium(VI) complex [UO2((R,S)-1,1'-binaphthylene-2,2'-dicarboxylate)(H2O)] was obtained by the hydrothermal treatment of UO2(NO3)(2)center dot 6H(2)O with (R,S)-1,1'-binaphthylene-2,2'-dicarboxylic acid(BCA) (L) in water at 180 degrees C in Pyrex tube. The crystal belongs to monoclinic system, space group C2/c, with a=1.640 3(3) nm, b=1.1967(2) nm, c=1.066 3(17) nm, beta=104.412(4)degrees, V=2.0272(6) nm(3), Z=4. CCDC: 659617.

• 出版日期2007-12
• 单位东南大学