A Highly Diastereoselective Access to Silicon-Containing Oxazines via the TMSOTf-Promoted Reactions of N-Benzoyl-N,O-acetals with Allyl Silanes

作者：Li Zheng Rong; Zhang Yuan Xiu; Tu Wei Ping; Yin Biao Lin^*

来源：Synlett, 2011, 2011(20): 2977-2980.

DOI：10.1055/s-0031-1289877

• N-benzoyl-N
• O-acetals
• oxazine
• cycloaddition
• dia-stereoselectivity

A TMSOTf-promoted cycloaddition of N-benzoyl-N, O-acetals with allyl silanes to synthesize silicon-containing oxazines with high diastereoselectivities has been developed. The obtained products might be useful as building blocks in organic synthesis.

• 出版日期2011-12
• 单位华南理工大学