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摘要
A novel ratiometric fluorescence sensing system for the ultrasensitive detection of Hg2+ was developed. It used aminofunctionalized silicon nanoparticles and rhodamine B, which exhibit two distinct fluorescence emission peaks at 449 and 581nm, respectively, under a single excitation wavelength (350nm). The fluorescence of the amino-functionalized silicon nanoparticles was selectively quenched by Hg2+, while that of rhodamine B was insensitive to Hg2+. The ratio of fluorescence intensities at 449-581nm linearly decreased with increasing concentrations of Hg2+ from 0.005-0.1 and 0.1-7 mu M within 0.5min, and a detection limit as low as 3.3nM was achieved. Moreover, the ratiometric fluorescence sensing system exhibited good selectivity toward Hg2+ over other metal ions with relatively low background interference, even in a complex matrix such as lake water. Most importantly, the practical use of this sensing system for Hg2+ detection in real water samples was also demonstrated.
- 出版日期2018
- 单位湖南师范大学
