A new reactive polymethacrylate bearing pendant furfuryl groups: Synthesis, thermoreversible reactions, and self-healing

作者：Jung Sungmin; Liu Jiang Tian; Hong Sung Hwa; Arunbabu Dhamodaran; Noh Seung Man; Oh Jung Kwon^*

来源：Polymer, 2017, 109: 58-65.

DOI：10.1016/j.polymer.2016.12.029

• Post-modification
• Furan-containing polymethacrylates
• Crosslinked networks
• Diels-Alder reaction
• Retro-Diels-Alder reaction
• Self-healing

We report a new methacrylate copolymer having pendant furfuryl groups (PFu) reactive to maleimide-bearing compounds to form thermally-induced crosslinked networks exhibiting self-healability through thermoreversible Diels-Alder (DA)/Retro-DA reactions. The PFu is synthesized by a combination of a facile radical polymerization with post-modification methods through a base-catalyzed coupling reaction and a thermally-induced thiol-ene radical addition reaction. The resulting PFu is effective toward DA reaction with a maleimide-bearing crosslinker at moderate or elevated temperatures, yielding highly crosslinked films through DA linkages. Thermal analysis and spectroscopic studies along with NMR model study with small molecular weight precursors suggest the formation of DA-crosslinked networks at 50-100 degrees C and the occurrence of retro-DA reaction at >125 degrees C. The resulting DA-crosslinked network is dynamic, exhibiting self-healing through the occurrence of thermoreversible DA/retro-DA reactions, confirmed with sol-gel transition and optical microscopy.

• 出版日期2017-1-27