A short and modular synthesis of bulky and electron-rich N-phosphinomethyl-functionalised N-heterocyclic carbene complexes

作者：Brill Marcel; Kuehnel Erik; Scriban Corina; Rominger Frank; Hofmann Peter^*

来源：Dalton Transactions, 2013, 42(36): 12861-12864.

DOI：10.1039/c3dt51777b

Bulky and electron-rich N-phosphinomethyl-substituted N-heterocyclic carbene transition metal complexes have been prepared in a short and efficient protocol. The modular synthesis allows one to convert borane-protected phosphino-functionalized imidazolium salts into their corresponding metal chelate complexes in a one-pot procedure.

• 出版日期2013