PhI(OAc)(2)/I-2 induced aziridination of alkenes with TsNH2 under mild conditions

作者：Fan Renhua^*; Pu Dongming; Gan Jianhong; Wang Bing

来源：Tetrahedron Letters, 2008, 49(33): 4925-4928.

DOI：10.1016/j.tetlet.2008.05.143

The aziridination of alkenes with the direct use of p-toluenesulfonamide (TsNH2) was achieved by using PhI(OAc)(2) and I-2 under mild conditions. The reaction affords aziridines in moderate to good yields, and offers good manipulability by avoiding the use of the expensive metal catalyst and the unstable and explosive PhI=NTs.

• 出版日期2008-8-11
• 单位复旦大学; 上海海洋大学