Determination of nitrocellulose by capillary electrophoresis with laser-induced fluorescence detection

作者：Fernandez de la Ossa Ma Angeles; Torre Mercedes; Garcia Ruiz Carmen^*

来源：Analytica Chimica Acta, 2012, 745: 149-155.

DOI：10.1016/j.aca.2012.07.032

• Nitrocellulose
• APTS
• Smokeless Gunpowder
• Collodion
• Explosives
• Capillary electrophoresis

The industrial application of nitrocellulose depends on its nitrogen content. When nitrocellulose presents high nitrogen content is used in the manufacture of explosives whereas nitrocellulose with low nitrogen content is used to make a wide range of daily and non-explosive products (e.g. cigarettes, paints, lacquers). This fact makes really important to develop a method for the determination and discrimination of nitrocellulose samples. This work reports, for the first time, the qualitative determination of nitrocellulose previously derivatized with 8-aminopyrene-1,3,6-trisulfonic acid (APTS) by capillary electrophoresis (CE-LIF) with laser-induced fluorescence detection (CE-LIF). APTS-labeled nitrocellulose was determined in lowly and highly nitrated nitrocellulose samples present in collodions and smokeless gunpowders, respectively, after their pulverization in liquid nitrogen. The method described enables the visual discrimination of different nitrocelluloses on the basis of the different electrophoretic profiles obtained, and provides a useful tool to determine nitrocellulose. Additionally, the use of field-amplified sample injection (FASI) enabled enhanced sample detection, which made it possible to determine nitrocellulose contained in similar to 15 mu g of gunpowder.

• 出版日期2012-10-1