A Mn(II) coordination framework incorporating the redox-active tris(4-(pyridin-4-yl)phenyl)amine ligand (NPy3): electrochemical and spectral properties

作者：Hua Carol^*; D'Alessandro Deanna M

来源：CrystEngComm, 2014, 16(28): 6331-6334.

DOI：10.1039/c3ce42603c

A new multifunctional coordination framework, [Mn(NPy3)Cl center dot 3MeOH center dot DMF](n), containing the redox-active tris(4-(pyridine-4-yl)phenyl)amine ligand (NPy3) was synthesised and characterised. The redox properties of the framework were investigated, and the oxidised state of the framework was generated chemically and spectroelectrochemically. This material exhibits multifunctionality by virtue of its ability to switch the fluorescence 'on' and 'off' with the redox state.

• 出版日期2014