Aromatic poly(arylene ether urea) with high dipole moment for high thermal stability and high energy density capacitors

作者：Cheng Zhaoxi; Lin Minren; Wu Shan; Thakur Yash; Zhou Yue; Jeong Dae Yong; Shen Qundong; Zhang Q M^*

来源：Applied Physics Letters, 2015, 106(20): 202902.

DOI：10.1063/1.4921485

Developing dielectric polymers with higher dielectric constant without sacrificing loss and thermal stability is of great importance for next generation of high energy density capacitors. We show here that by replacing the CH2 group in the aromatic polyurea (ArPU) with the polar ether group, thus raising the dipole moment of the molecular unit, poly(arylene ether urea) (PEEU) shows an increased dielectric constant of 4.7, compared with 4.2 of ArPU. Moreover, PEEU maintains the low dielectric loss and is thermally stable up to 250 degrees C. As a result, the polymer delivers 13 J/cm(3) discharged energy density at room temperature and 9 J/cm(3) at 120 degrees C. The high quality films perform well in terms of both breakdown strength (at 700 MV/m at room temperature) and leakage current from room temperature to elevated temperature. At 120 degrees C, the breakdown strength is 600 MV/m and the conductivity is 1.58 x 10(-14) S/cm measured under 100 MV/m.

• 出版日期2015-5-18
• 单位南京大学