A recyclable and highly active Co3O4 nanoparticles/titanate nanowire catalyst for organic dyes degradation with peroxymonosulfate

作者：Chen Zhili; Chen Shihua; Li Yonghe; Si Xiaolei; Huang Jun; Massey Sylvain; Chen Guangliang^*

来源：Materials Research Bulletin, 2014, 57: 170-176.

DOI：10.1016/j.materresbull.2014.05.046

• Co3O4 nanoparticles
• Titanate nanowires
• Heterostructure catalyst
• Organic dyes
• Oxone

In this paper, we reported a recyclable and highly active porous catalyst of titanate nanowires (TNWs) coated with well-distributed Co3O4 nanoparticles (NPs) (Co3O4/TNWs). Sodium ions of TNWs were exchanged with hydrogen ions in the dilute nitric acid, and this protocol was very suitable for capturing cobalt ions. X-ray diffraction (XRD) demonstrated the existence of Co3O4 phase with unique lattice planes, such as (2 2 0), (3 11) and (511). Electron microscopes (FE-SEM and TEM) indicated that the Co3O4 NPs with an average diameter of 22 +/- 3 nm were coated uniformly on TNWs surface (average diameter: 37 +/- 5.5 nm), and the Co3O4 NPs mainly exposed their (2 2 0) and (2 2 2) active planes. XPS analysis confirms the formation of Co3O4 phase by the presence of Co 2p peaks at 780.1 eV (2p 3/2) and 795.5 eV (2p 1/2). Methylene blue (MB) and other organic dyes (rhodamine B (RhB) and methyl orange (MO)) were chosen as target compounds for catalytic degradation under indoor scattering light. Compared to the original Co3O4/TNWs catalyst, the catalytic efficiency of nanoscaled catalyst with oxone for MB was about 15 times higher, and the MB solution (10 mg L-1) was completely degraded within 8 min. The catalytic activity of recycled catalyst used in the sixth run still remained very active, and the degradation time for MB was only 16 min. The nanosized catalyst also had a high activity for dyes of RhB (10 mg L-1) and MO (10 mg L-1), as the degradation efficiencies of RhB and MO after 10 min of contact time were about 90.2% and 92.6%, respectively.

• 出版日期2014-9
• 单位浙江理工大学