摘要
Ionomer derivatives of brominated poly(isobutylene-co-isoprene) rubber (BIIR) are prepared by alkylation of PPh(3), imidazole and 2-[2-(dimethylamino) ethoxy] ethanol under solvent-free conditions. Halide displacement is shown to be accompanied by allylic bromide rearrangement to kinetically more reactive endo-allylic bromide isomers. Alkylation to give quaternary onium-halide salts produces an isomerisation catalyst in situ, owing to a rapid S(N)2' isomerisation by free bromide. As a result, a continuous process for PPh3 alkylation can be catalyzed by the recycling of a small amount of IIR-PPh(3)Br product to the feed, thereby supporting an irreversible ionomer synthesis that proceeds to full conversion without the generation of reaction byproducts.
- 出版日期2011