Direct Electrochemical Synthesis of an Unusual Complex Salt: Almost Structural Identity - Different Charge

作者：Oppermann Alexander; Wehrhahn Christoph; Floerke Ulrich; Herres Pawlis Sonja; Henkel Gerald

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2017, 643(3): 266-275.

DOI：10.1002/zaac.201600408

• Thiolate
• Copper
• Density functional calculations ( DFT)
• Molecular structure
• Electrochemical synthesis

The electrochemical synthesis is an underestimated synthesis protocol, which can lead to unexpected results. We obtained an unusual Cu-I complex salt with a pentanuclear anion and a heptanuclear cation. The anion [Cu-5(StBu)(6)]- features a trigonal prism coordination motif with a twisted arrangement. The cation [Cu-7(StBu)(6)(bipy)(3)](+) is structurally almost identical to the anion and shares therefore basic building principles. These Cu-S skeletons with additional N donor

• 出版日期2017-2