A Facile Route to Synthesize Sheet-like Na2Ti3O7 with Improved Sodium Storage Properties

作者：Xie Man; Wang Kangkang; Chen Renjie^*; Li Li; Wu Feng

来源：Chemical Research in Chinese Universities, 2015, 31(3): 443-446.

DOI：10.1007/s40242-015-4422-x

• Na2Ti3O7
• Sodium-ion battery
• Anode
• Hollow sphere TiO2

A high purity sheet-like Na2Ti3O7 material was synthesized by a new facile solid-state method with hollow sphere TiO2 as titanium source. X-Ray diffraction(XRD) measurement proves that no impurity phase existed when the sample was heated at 900 degrees C. Charge/discharge measurement was performed in a potential range of 0.01-2.5 V at different current-rates(C-rates). The initial charge/discharge capacities are 191/424 mA.h/g at 0.1 C and still remain as high as 101 mA.h/g after 50 cycles. CV test proves that the large irreversible capacity in the initial cycle results from the formation of the solid electrolyte interface(SEI). However, the electrode presents an increased initial coulombic efficiency in a 1 mol/L NaPF6 electrolyte compared to that in a 1 mol/L NaClO4 electrolyte.

• 出版日期2015-6
• 单位北京理工大学