A Supramolecular Copper(II) Complex Bearing Salen-Type Bisoxime Ligand: Synthesis, Structural Characterization, and Thermal Property

作者：Zhao Li; Wang Li; Sun Yin Xia; Dong Wen Kui^*; Tang Xiao Lu; Gao Xiong Hou

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2012, 42(9): 1303-1308.

DOI：10.1080/15533174.2012.684235

• Cu-II complex
• Salen-type ligand
• supramolecular structure
• synthesis
• thermal property

A supramolecular Cu-II complex, [Cu(L)(H2O)] (H2L: 4,4',6,6'-tetrachloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol), has been synthesized and structurally characterized. X-ray crystallographic analysis shows that the complex is a centrosymmetric mononuclear Cu-II complex, and the Cu-II atom is penta-coordinated by two phenolic O atoms and two oxime N atoms from the deprotonated Salen-type ligand, and one oxygen atom from the coordinated water molecule. A self-assembling continual supramolecular structure is formed by intermolecular O3-H3 center dot center dot center dot O2 and O3-H3 center dot center dot center dot Cl1 hydrogen bonds.

• 出版日期2012
• 单位兰州交通大学