An unusual axial-axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters

作者：Naiya Subrata; Biswas Saptarshi; Drew Michael G B; Ghosh Ashutosh^*

来源：Inorganic Chemistry Communications, 2012, 20: 286-289.

DOI：10.1016/j.inoche.2012.03.030

• Hydrogen-bonded
• Chlorine-water cluster
• Chair conformation
• X-ray diffraction analysis
• Decahydronaphthalene

An alternating hexameric water (H2O)(6) cluster and a chlorine-water cluster [Cl-2(H2O)(4)](2-) in the chair forms combine axially to each other to form a 1D chain [{Cl-2(H2O)(6)}(2-)](n) in complex [FeL2]Cl center dot(H2O)(3) (L=2-[(2-methylaminoethylimino)-methyl]-phenol)]. The water molecules display extensive H-bonding interactions with monomeric iron-organic units to form a hydrogen-bonded 2D supramolecular assembly.

• 出版日期2012-6