Application of Ionic Liquids in Organic Synthesis Promoted by Microwave Irradiation

作者：Ying Anguo^*; Chen Xinzhi; Ye Weidong; Zhang Dingfeng; Liu Luo; Chen Jianhui

来源：Progress in Chemistry, 2008, 20(11): 1642-1650.

• ionic liquids
• microwave irradiation
• organic synthesis
• recycle

Application of ionic liquids in organic synthesis promoted by microwave irradiation as a new green methodology has been attracting great interests. Microwave-assisted organic transformations, using ionic liquids as reaction medium or catalysts, have great advantages in accelerating reaction rate, obtaining products with high recovery yield and good selectivity, ease of work-up, as well as recycling usage of ionic liquids after simply regeneration. The paper reviews the progress of ionic liquids as microwave mediums or catalysts in the fields of organic synthesis, mainly including cyclization, nucleophilic substitution, ring closing metathesis, acylation, rearrangement, polymerization, coupling, oxidation and reduction as well as selective debromination, etc.

• 出版日期2008-11
• 单位浙江大学