摘要

Recent developments in asymmetric catalytic reactions under solvent-free conditions were reviewed. The article mainly discussed asymmetric Aldol reaction, asymmetric ring-opening reaction, kinetic resolution of racemic epoxides, asymmetric Diels-Alder reaction, asymmetric addition of organometallic reagents to aldehydes and ketones, asymmetric hydrogenation, asymmetric hydroformylation, asymmetric metathesis reaction, asymmetric Michael addition reaction, asymmetric oxidation and asymmetric Friedel-Crafts reaction. The prospect of asymmetric catalytic reactions under solvent-free condition was also proposed.