Nanocrystalline ZnCO3-A novel sorbent for low-temperature removal of H2S

作者：Balichard Kevin; Nyikeine Camille; Bezverkhyy Igor^*

来源：Journal of Hazardous Materials, 2014, 264: 79-83.

DOI：10.1016/j.jhazmat.2013.10.068

• H2S removal
• H2S capture
• Zinc carbonate sulfidation

The reactivity of a nanocrystalline ZnCO3 toward H2S (0.2 vol% in N-2/H-2 mixture) at 140-180 degrees C was characterized by thermal gravimetric analysis and by breakthrough curves measurements. We have found that under used conditions transformation of ZnCO3 into ZnS is complete and the rate determining step of the sulfidation is the surface reaction. Such behavior is in strike contrast with that of ZnO whose sulfidation is severely limited by diffusion. The higher reactivity of ZnCO3 in comparison with ZnO is attributed to the different microstructure of ZnS layer formed in these materials after a partial sulfidation. As in ZnO-ZnS transformation the molar volume increases (from 14.5 to 23.8 cm(3)/mol), a continuous protective ZnS layer is formed hampering the access of H2S to the non reacted ZnO core. By contrast, in ZnCO3-ZnS transformation the molar volume decreases (from 27.9 to 23.8 cm(3)/mol), which produces a discontinuous non-protective ZnS layer enabling a complete transformation of ZnCO3 even at 140 degrees C. The higher reactivity of ZnCO3 results in a considerable increase of the breakthrough sulfur capacity of the carbonate in comparison with oxide. The material has therefore a good potential for being used as a disposable sorbent for H2S capture at low temperature.

• 出版日期2014-1-15