摘要

The influence of a pressure of 60 MPa on the conversion and the stereoselectivity of the Diels-Alder reaction of 2- and 3-furylmethanol with methyl-, benzyl-, and phenylmaleimide was studied in a capillary micro-reactor In the case of 2-furylmethanol, a 17-fold higher conversion was obtained at 60 MPa with respect to 0 1 MPa experiments Pressure positively affects the formation of the exo isomer, whereas in the case of 3-furylmethanol pressure does not affect the reaction

  • 出版日期2010-4