Dynamic Assembly of Porphyrin Wires Trapped on a Highly Oriented Pyrolitic Graphite Surface

作者:Rauch Vivien; Wytko Jennifer A; Takahashi Mayuko; Kikkawa Yoshihiro*; Kanesato Masatoshi; Weiss Jean
来源:Organic Letters, 2012, 14(8): 1998-2001.
DOI:10.1021/ol300488y

摘要

Carefully designed porphyrin building blocks assemble through selective imidazole binding in various solvents to form linear multiporphyrin objects. From a dynamic mixture of monomers, dimers, and oligomers, linear objects were observed on a highly oriented pyrolitic graphite (HOPG) surface. On the surface, the objects%26apos; morphology clearly depended on the solvent used for deposition and was modified upon heating.

  • 出版日期2012-4-20